منابع مشابه
A Critical Appraisal of RAFT-Mediated Polymerization-Induced Self-Assembly.
Recently, polymerization-induced self-assembly (PISA) has become widely recognized as a robust and efficient route to produce block copolymer nanoparticles of controlled size, morphology, and surface chemistry. Several reviews of this field have been published since 2012, but a substantial number of new papers have been published in the last three years. In this Perspective, we provide a critic...
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In this Perspective, we discuss the recent development of polymerization-induced self-assembly mediated by reversible addition-fragmentation chain transfer (RAFT) aqueous dispersion polymerization. This approach has quickly become a powerful and versatile technique for the synthesis of a wide range of bespoke organic diblock copolymer nano-objects of controllable size, morphology, and surface f...
متن کاملEmergent Properties of Giant Vesicles Formed by a Polymerization-Induced Self-Assembly (PISA) Reaction
Giant micrometer sized vesicles are of obvious interest to the natural sciences as well as engineering, having potential application in fields ranging from drug delivery to synthetic biology. Their formation often requires elaborate experimental techniques and attempts to obtain giant vesicles from chemical media in a one-pot fashion have so far led to much smaller nanoscale structures. Here we...
متن کاملPermeable Protein-Loaded Polymersome Cascade Nanoreactors by Polymerization-Induced Self-Assembly
Enzyme loading of polymersomes requires permeability to enable them to interact with the external environment, typically requiring addition of complex functionality to enable porosity. Herein, we describe a synthetic route towards intrinsically permeable polymersomes loaded with functional proteins using initiator-free visible light-mediated polymerization-induced self-assembly (photo-PISA) und...
متن کاملPhotoinitiated Polymerization‐Induced Self‐Assembly (Photo‐PISA): New Insights and Opportunities
The polymerization-induced self-assembly (PISA) process is a useful synthetic tool for the efficient synthesis of polymeric nanoparticles of different morphologies. Recently, studies on visible light initiated PISA processes have offered a number of key research opportunities that are not readily accessible using traditional thermally initiated systems. For example, visible light mediated PISA ...
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ژورنال
عنوان ژورنال: Macromolecular Rapid Communications
سال: 2019
ISSN: 1022-1336
DOI: 10.1002/marc.201800885